H+ gas
Information
Assumptions:
- The radius (for the purpose of the rigid-sphere assumption of
kinetic theory) is that of H
(http://en.wikipedia.org/wiki/Hydrogen).
Additional notes:
- The default reference enthalpy is zero at 25 °C.
- The source data [McBride2002] breaks the
data into three
temperature ranges, but the constants are the same for each.
Therefore, the temperature limits are set here such that the entire
range is handled without switching.
The lower temperature limit in the source data
is 298.150 K, but here it is expanded down to 200 K. The constants are
independent of temperature anyway.
- The enthalpy to produce H+ from H2O
(H2O ⇀ OH- + H+) is
-96569.804 J/mol. The enthalpy to produce H+ from H3O+
(H3O+ ⇀ H2O + H+) is
839826.0 J/mol. Based on
[Tissandier1998], the
enthalpy of formation of aqueous H+ is 1150.1e3 J/mol.
For more information, please see the
Characteristic package.
Extends from
BaseClasses.Characteristic (Package of thermodynamic and diffusive properties).